Experimental and theoretical study of lanthanide complexes based on linear and macrocyclic polyaminopolycarboxylic acids containing pyrazolylethyl arms.

نویسندگان

  • Elena Pérez-Mayoral
  • Elena Soriano
  • Sebastián Cerdán
  • Paloma Ballesteros
چکیده

We report the synthesis of two novel Gd(III)-complexes derived from linear and macrocyclic polyaminopolycarboxylic acids 1 and 2, which contain a 3,5- dimethylpyrazolyl-ethyl arm, and a study of their relaxivity properties. The relationships between the experimental and theoretical results have provided interesting information about the kinetic and thermodynamic stability of these complexes.

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عنوان ژورنال:
  • Molecules

دوره 11 5  شماره 

صفحات  -

تاریخ انتشار 2006